A new method for the preparation of SERS active Cu electrode surfaces with high enhancement factors, which enable the observation of high quality spectra in the low-frequency region at different chloride concentrations, is proposed. Low-frequency modes at 160 and 145 cm-t are attributed to Cu-Cu vib
Enhanced Raman scattering from iron electrodes
β Scribed by G. Mengoli; M.M. Musiani; M. Fleischman; B. Mao; Z.Q. Tian
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 513 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0013-4686
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β¦ Synopsis
It is shown that the enhanced Raman spectra of pyridine adsorbed on Fe can be obtained by depositing thin films of Fe onto roughened Ag substrates. An alternative strategy of inducing enhanced scattering is also explored which relies on the deposition of a low density of small growth centres of Ag on Fe by simple displacement reaction followed by dissolution of the smooth substrate; this procedure gives electrodes which show spectra both of Ag and/or Fe depending on the position of illumination.
π SIMILAR VOLUMES
SERS from crystal rlolct (CV) on a Ag clectrodc was mvcslqakd under prcrrsonsncc and resonance condltlons. The ckcll~llon prolilc of the chcmaorbcd spccics is Me that of chsrolvcd mokculcs but mtcnsltirs ZUIL' =I000 tnncs luger. The Raman enhancement IS = IO8 and ckhlblts 3 spcc~lic potcntlal dcpcnd