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Enhanced enantioselectivity of Candida rugosa lipase in ionic liquids as compared to organic solvents

✍ Scribed by Olga Ulbert; Tamás Fráter; Katalin Bélafi-Bakó; László Gubicza

Book ID
113803850
Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
180 KB
Volume
31
Category
Article
ISSN
1381-1177

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Candida rugosa lipase-catalyzed enantios
Candida rugosa lipase-catalyzed enantioselective hydrolysis in organic solvents. Convenient preparation of optically pure 2-hydroxy-2-arylethanephosphonates
✍ Yonghui Zhang; Zuyi Li; Chengye Yuan 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 65 KB

A convenient enzymatic method is presented for the preparation of optically pure 2-hydroxy-2-arylethanephosphonates. It is proved that 2-butyryloxy-2-arylethanephosphonates can be enantioselectively hydrolyzed in diisopropyl ether equilibrated with water to give both isomers in high yield and excell