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[(enH2)0.5][Zr2(PO4)2(HPO4)F]·H2O: A Unique Zirconium Fluoride Phosphate with a Cavity Structure

✍ Scribed by Prof. Dr. Erhard Kemnitz; Dipl.-Chem. Martin Wloka; Dr. Sergej Trojanov; Dipl.-Chem. Anja Stiewe

Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
309 KB
Volume
35
Category
Article
ISSN
0044-8249

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ChemInform Abstract: (enH2)0.5(Zr2(PO4)2
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1997 zirconium, Zr zirconium, Zr I 4400 08 -015 (enH2)0.5(Zr2(PO4)2(HPO4)F)•H2O (I), a Novel Zirconium Fluoride Phosphate with Open-Framework Structure. -The title compound (I), prepared by hydrothermal reaction of ZrOCl2. times.8 H2O, ethylenediamine monohydrate, H3PO4, and HF at 180 • C, represen

(enH2)0.5[Zr2(PO4)2(HPO4)F]·H2O — ein ne
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Mittelgroße Kanäle durchziehen die Struktur des ersten Zirconiumfluoridphosphats, das jetzt synthetisiert worden ist (Strukturausschnitt im Bild). Das Gerüst wird aus ZrO~6~‐ und ZrO~5~F‐Oktaedern sowie PO~4~‐ und PO~3~(OH)‐Tetraedern aufgebaut. Durch Variation des als Templat verwendeten Amins soll

ChemInform Abstract: Unique Charge Order
ChemInform Abstract: Unique Charge Ordering of Manganese in a New Mixed Valent Phosphate K3Mn3IIMnIII(PO4) (H0.5PO4)2(HPO4)2.
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