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Energy transfer in polymers—I. Triplet-triplet transfer in solid polyvinylbenzophenone-naphthalene system

✍ Scribed by C. David; W. Demarteau; G. Geuskens

Publisher
Elsevier Science
Year
1970
Tongue
English
Weight
378 KB
Volume
6
Category
Article
ISSN
0014-3057

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✦ Synopsis

Energy transfer has been shown to occur from triplet polyvinylbenzophenone to naphthalene by an exchange mechanism at liquid nitrogen temperature. The radius of the Terenin "critical sphere" is much larger for the polymer containing naphthalene (29.3,) than for mixtures benzophenonenaphthalene in organic glasses (11 A.). The results are interpreted in terms of energy migration in the polymer according to Voltz theory.

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