Energy transfer between Ce3+ and Tb3+ in rare earth pentaphosphates
โ Scribed by B. Blanzat; J.P. Denis; R. Reisfeld
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- English
- Weight
- 240 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
Energy transfer between Ce3+ and Tb3+ in rare earth pentaphosphates was studied versus Ce3+ concentration and temperature. Within this chain-type structure the energy diffusion is very sensitive to atomic substitution and -this process is operating via the Ln-0-P-0-Ln links. The energy transfer efficiency is strongly influenced by the effect of temperature on the overlap between the CeW and Tb* bands.
๐ SIMILAR VOLUMES
Energy transfer (ET) between Cc3++ Tm3+ and Ce3++ Tb3+ in p h osphate glass was measured in the temperature range 7-300 K. The efficiency of ET between Ce3' and Tm3+ is independent of temperature, while temperature increasr; is observed in the Ce3+-Tb3+ pair. This is explained by the increase with t
Excitation of Tb3+ and Eu3+in DSlSO with 487 mp, which corresponds to the 'I-'6 + 'Da transition of T%j', is accompanied by a reduction in the flt~orerccnce efficiency of Tb3+ as [Eu3'] increases and by thz appearance of a wx:nk emission from Eu3+. An nvcrage rntc constant for both the fluorescence