## Using translationally excited H atoms generated by laser photolysis of H2S at 193 nm, the reaction dynamics of H + H,O+OH + H2 and H + COIdOH + CO was investigated at collision energies of 2.2 and 2.3 eV, respectively. Nascent OH rotational and vibrational quantum-state distributions and OH pro
Energy partitioning in the reaction OH + CO → CO2 + H
✍ Scribed by Daniel W. Trainor; C.W. Vonrosenberg Jr.
- Publisher
- Elsevier Science
- Year
- 1974
- Tongue
- English
- Weight
- 463 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
The results of an experimental investigation designed to determine t-he vibrational energy content in the praducts of the reaction OH + CO + CO* + H are presented. No 1R emission wm observed in any of the fundamental or strong combination bands of C02, 3nd thus OUT results are expressed as bounds on the percent of exothermicity occurring in a particular vibrational energy state. These observalikk are discussed in relation to transition stite theory and other related experimental results on th& raction.
📜 SIMILAR VOLUMES
The rate coefficient of the reaction H + CO z ~ CO + OH (1) was measured using OH concentration measurements in shock-heated N20-H2-CO 2 mixtures and through the inhibiting effect of CO 2 on methane ignition. For 2170 < T < 3150 K the two methods give concordant results and imply k I = 2.0 × 1014exp
The reaction energy ofthe hydrogen elimination from H,CO is calculated using complete fourth-order many-body permrbation theory (MBPT) and the coupled cluster (CC) methad including up to triple excitation operators. For a number of basis sets the CC reaction energy IS closer to the experimental valu