𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Energy partitioning in the reaction OH + CO → CO2 + H

✍ Scribed by Daniel W. Trainor; C.W. Vonrosenberg Jr.


Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
463 KB
Volume
29
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis


The results of an experimental investigation designed to determine t-he vibrational energy content in the praducts of the reaction OH + CO + CO* + H are presented. No 1R emission wm observed in any of the fundamental or strong combination bands of C02, 3nd thus OUT results are expressed as bounds on the percent of exothermicity occurring in a particular vibrational energy state. These observalikk are discussed in relation to transition stite theory and other related experimental results on th& raction.


📜 SIMILAR VOLUMES


Reaction dynamics, OH energy partitionin
✍ A. Jacobs; H.-R. Volpp; J. Wolfrum 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 813 KB

## Using translationally excited H atoms generated by laser photolysis of H2S at 193 nm, the reaction dynamics of H + H,O+OH + H2 and H + COIdOH + CO was investigated at collision energies of 2.2 and 2.3 eV, respectively. Nascent OH rotational and vibrational quantum-state distributions and OH pro

High-temperature measurements of the rat
✍ V. Lissianski; H. Yang; Z. Qin; M.R. Mueller; K.S. Shin; W.C. Gardiner Jr. 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 412 KB

The rate coefficient of the reaction H + CO z ~ CO + OH (1) was measured using OH concentration measurements in shock-heated N20-H2-CO 2 mixtures and through the inhibiting effect of CO 2 on methane ignition. For 2170 < T < 3150 K the two methods give concordant results and imply k I = 2.0 × 1014exp

Can the coupled cluster method improve m
✍ Miroslav Urban; Vladimir Kellö; Ivan Černušák; Jozef Noga; Geerd H.F. Diercksen 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 600 KB

The reaction energy ofthe hydrogen elimination from H,CO is calculated using complete fourth-order many-body permrbation theory (MBPT) and the coupled cluster (CC) methad including up to triple excitation operators. For a number of basis sets the CC reaction energy IS closer to the experimental valu