✍ Scribed by Peter A. Tanner
No coin nor oath required. For personal study only.
The excitation, electronic absorption and luminescence spectra of cubic CQN~HOBI~ have been recorded at temperatures down to that of liquid helium. The detailed spectral analyses enable comparisons to be made of the crystal-field splittings of Russell-Saunders terms with those in C~NakIoCle. Under intense 647.1 mn laser excitation, luminescence is observed in the neat material ln the spectral region between 17800 and 21750 cm-l.
📜 SIMILAR VOLUMES
A theoretical study of the spectroscopy of HOBr and its deuterated isotopomer is presented. Highly accurate ab initio potential energy and dipole moment surfaces have been determined at the multireference configuration interaction level of theory, with large triple-~" quality basis sets. From the an
The \(\nu_{1}\) band of \(\mathrm{HOBr}\) centered at \(3614.903 \mathrm{~cm}^{-1}\) has been observed at \(0.006 \mathrm{~cm}^{-1}\) resolution. The band is a hybrid type with \(\left|\left(\partial \mu_{b} / \partial Q_{1}\right) /\left(\partial \mu_{a} / \partial Q_{1}\right)\right| \approx 0.84\