The proton affinity of HOBr
β Scribed by Timothy J. Lee; Joseph S. Francisco
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 351 KB
- Volume
- 251
- Category
- Article
- ISSN
- 0009-2614
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π SIMILAR VOLUMES
The \(\nu_{1}\) band of \(\mathrm{HOBr}\) centered at \(3614.903 \mathrm{~cm}^{-1}\) has been observed at \(0.006 \mathrm{~cm}^{-1}\) resolution. The band is a hybrid type with \(\left|\left(\partial \mu_{b} / \partial Q_{1}\right) /\left(\partial \mu_{a} / \partial Q_{1}\right)\right| \approx 0.84\
The absolute proton affinity (PA) of aromatic carbons of monosubstituted naphthalenes with CH 3 , OH, CHO, NO 2 and Cl substituents was calculated at the MP2(fc)/6-31G\*\*//HF/6-31G\* ZPVE(HF/6-31G\*) level of theory. Increments corresponding to unsubstituted positions within the naphthalene skeleto
Threshold photoionization mass spectrometry has been used to measure the appearance energies for the formation of C,H; from isobutane, neopentane and tert-butyl iodide. From the value of 10.821 \*0.008 eV for isobutane, a 298 K heat of formation for the tert-butyl cation of 711.4 f 1.1 kJ mol-' is d