𝔖 Bobbio Scriptorium
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The proton affinity of HOBr

✍ Scribed by Timothy J. Lee; Joseph S. Francisco


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
351 KB
Volume
251
Category
Article
ISSN
0009-2614

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The \(\nu_{1}\) band of \(\mathrm{HOBr}\) centered at \(3614.903 \mathrm{~cm}^{-1}\) has been observed at \(0.006 \mathrm{~cm}^{-1}\) resolution. The band is a hybrid type with \(\left|\left(\partial \mu_{b} / \partial Q_{1}\right) /\left(\partial \mu_{a} / \partial Q_{1}\right)\right| \approx 0.84\

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The absolute proton affinity (PA) of aromatic carbons of monosubstituted naphthalenes with CH 3 , OH, CHO, NO 2 and Cl substituents was calculated at the MP2(fc)/6-31G\*\*//HF/6-31G\* ZPVE(HF/6-31G\*) level of theory. Increments corresponding to unsubstituted positions within the naphthalene skeleto

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Threshold photoionization mass spectrometry has been used to measure the appearance energies for the formation of C,H; from isobutane, neopentane and tert-butyl iodide. From the value of 10.821 \*0.008 eV for isobutane, a 298 K heat of formation for the tert-butyl cation of 711.4 f 1.1 kJ mol-' is d