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Energy barriers to the enantiotopomerisation of tetrahedral boron chelates: a rearrangement of some cyclic boron compounds

✍ Scribed by Boulton, A. J.; Prado, Carlos Seoane


Book ID
120582932
Publisher
The Royal Society of Chemistry
Year
1982
Tongue
English
Weight
125 KB
Volume
17
Category
Article
ISSN
0022-4936

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tetracarbonylchromium complexes / 1,2,3,4-Diphosphadiboretane, isomerisation of 1,2,3,4-diphosphadiboretane (1) reacts with Fe2(CO)9 to give two isomeric tetracarbonyliron complexes 2, 3 with P-Fe bonds and a bis(tetracarbony1iron) complex 4. In contrast, 1 displaces the olefinic ligand from tetrac