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“Ene-type” addition of alkenes to phenyl vinylsulfoxide

✍ Scribed by Marie-Héléne Brichard; Zdenek Janousek; Robert Merényi; Heinz G. Viehe

Book ID
104225197
Publisher
Elsevier Science
Year
1992
Tongue
French
Weight
187 KB
Volume
33
Category
Article
ISSN
0040-4039

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✦ Synopsis

Phenyl vinylsulfoxide reacts under acylating conditions PA, TFAA) with isobutene to give double "ene" a$adduct Rope and other akenes examined afford a f%-"ene" aikylation accompanied by trifluomacctox ylation at tie same carbon atom.

📜 SIMILAR VOLUMES

Addition of alkenes to phenyl-substitute
Addition of alkenes to phenyl-substituted enol radical cations, C6H5C(OH)CHR+˙
✍ P. Mourgues; J. P. Denhez; H. E. Audier; S. Hammerum 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 English ⚖ 440 KB

The addition-fragmentation reactions of phenyl-substituted enol radical cations, C6H5C(OH)CHR+' (R = H, CH,), with alkenes were studied by Fourier transform ion cyclotron resonance spectroscopy. These reactions (involving both labelled and unlabelled reactants) were compared with the unimolecular re