✦ LIBER ✦

Addition of alkenes to phenyl-substituted enol radical cations, C6H5C(OH)CHR+˙

✍ Scribed by P. Mourgues; J. P. Denhez; H. E. Audier; S. Hammerum

Book ID: 102559524
Publisher: John Wiley and Sons
Year: 1993
Tongue: English
Weight: 440 KB
Volume: 28
Category: Article
ISSN: 1076-5174
DOI: 10.1002/oms.1210280310

No coin nor oath required. For personal study only.

✦ Synopsis

The addition-fragmentation reactions of phenyl-substituted enol radical cations, C6H5C(OH)CHR+' (R = H, CH,), with alkenes were studied by Fourier transform ion cyclotron resonance spectroscopy. These reactions (involving both labelled and unlabelled reactants) were compared with the unimolecular reactions of aromatic ketone molecular ions and related species that give rise to C6HSC(OH)CHR+' and alkene products. It is shown that the phenyl-substituted enol ions react with alkenes by C -C bond formation leading to an intermediate y- distonic ion; the reactions are not accompanied by cyclization to cyclobutanol intermediates.

📜 SIMILAR VOLUMES

The Chemistry of C6H6O radical cations:

The Chemistry of C6H6O radical cations: A study of rearrangement reactions of halogen substituted ethyl phenyl ethers

✍ D. H. Russell; M. L. Gross; J. Van Der Greef; N. M. M. Nibbering 📂 Article 📅 1979 🏛 John Wiley and Sons 🌐 English ⚖ 792 KB

Oxidative addition of phenols to bis(tri

Oxidative addition of phenols to bis(tricyclohexylphosphine)palladium. Synthesis and structural characterization of trans-[Pd(PCy3)2(H)(OC6H5)].C6H5OH (1) and trans-[Pd(PCy3)2(H)(OC6F5)].C6F5OH (2)

✍ Di Bugno, C.; Pasquali, M.; Leoni, P.; Sabatino, P.; Braga, D. 📂 Article 📅 1989 🏛 American Chemical Society 🌐 English ⚖ 653 KB

Synthetic and mechanistic studies of the

Synthetic and mechanistic studies of the addition of 4-chloroaniline to tricarbonyl (1–5-η-dienyl)iron(II) cations (dienyl = C6H7, 2-MeOC6H6 or C7H9)

✍ Timothy I. Odiaka 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 517 KB

The addition of halogenocarbons to alken

The addition of halogenocarbons to alkenes in the presence of [Mo2(CO)4(η-C5R5)2] (R = H, Me), [Mo2(CO)6(η-C5H5)2] and [{Mo(CO)3(η-C5H4)}2CH2]

✍ Reg Davis; Nasser M.S. Khazal; Thomas E. Bitterwolf 📂 Article 📅 1990 🏛 Elsevier Science 🌐 English ⚖ 473 KB

Kinetics of nucleophilic attack on co-or

Kinetics of nucleophilic attack on co-ordinated organic moieties. Part 17. Addition of pyridines to [Fe(1?5-?-dienyl)(CO)3]+ cations (dienyl = C6H7, 2-MeOC6H6, or C7H9)

✍ Odiaka, Timothy I.; Kane-Maguire, Leon A. P. 📂 Article 📅 1981 🏛 The Royal Society of Chemistry 🌐 English ⚖ 859 KB

Mechanisms of nucleophilic attack at coo

Mechanisms of nucleophilic attack at coordinated carbon monoxide: II. Iodide addition to a carbon monoxide ligand in [Fe(CO3 (1–5-η-dienyl)]+ cations (dienyl = C6H7, C7H9, 2-MeOC6H6)

✍ G.R. John; L.A.P. Kane-Maguire; R. Kanitz 📂 Article 📅 1986 🏛 Elsevier Science 🌐 English ⚖ 396 KB