ENDOR study of coals
โ Scribed by N.D. Yordanov; S. Duber; M. Zdravkova; T. Budinova
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 349 KB
- Volume
- 69
- Category
- Article
- ISSN
- 0016-2361
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โฆ Synopsis
Coals with carbon contents of 76 and 82 wt%, respectively, and their mixtures with ethylenediamine, were investigated by 'H ENDOR spectroscopy. In all cases the spectra obtained had a single line centred on the free proton frequency and one or two pairs of lines indicating a weak electron-nuclear interaction. The spectra for the coal/ethylenediamine mixtures differed from those for coals in a decreased value of splitting caused bv the electron-nuclear interaction. Differences in the splitting values observed were explained in terms of coal swelling by solvent.
๐ SIMILAR VOLUMES
E.p.r. and ENDOR measurements of five Argonne Premium Coal Samples (APCS) varying in rank from low-volatile (Pocahontas, No. 5) to lignite (Beulah-Zap, No. 8) either undoped or doped with nitroxide spin probes and a series of nitroxide radicals are reported. For the first time proton hyperline coupl
Racemic and achiral alkyl aryl nitroxides were examined at various temperatures. The restricted rotation of the aminoxyl substituents was indicated both by the ฮฒ-proton coupling constants and by the inequivalence of the aromatic ortho protons. These results are interpreted by the presence of two dif