Endor study of the 2-adamantyl radical
β Scribed by R.V. Lloyd; M.T. Rogers
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- English
- Weight
- 245 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0009-2614
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π SIMILAR VOLUMES
## Abstract The ENDOR spectrum was obtained for the benzo[__c__]cinnoline anion radicalin 1,2βdimethoxyethane. The hfs constants of the protons correspond with those found by EPR spectroscopy, and also agree well with the qualitative tendency of the reported spin density distributions by HMO calcul
The cation radical of canthaxanthin was generated electrochemically in dichloromethane and its solution ENDOR spectrum is reported for the first time. The isotropic proton hypertine coupling constants are in reasonable agreement with those calculated by RHF-INDO/SP molecular orbital methods for a pl
In the liquid crystal "Phase IV" which exhibits its nematic range between 16 and 76 "C ENDOR spectra of perinaphthenyi and tri-t-butylphencxyl radicals collld be recorded. it is demonstrated that the combined use of the ENDOR and liquid crystal methods yieIds valuabIe structural information.