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Endor investigations of biradicals in liquid crystals

✍ Scribed by Burkhard Kirste


Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
416 KB
Volume
130
Category
Article
ISSN
0009-2614

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πŸ“œ SIMILAR VOLUMES


Endor investigations of phenalenyl in po
✍ B. Kirste πŸ“‚ Article πŸ“… 1981 πŸ› Elsevier Science 🌐 English βš– 327 KB

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IN FROZEN LIQUD CRYSTU Burkhard KIRSTE and Hans VAN WILLICEN An ENDOR stud) ofvanadyl biucctylaccIon.nc (VO(xx)2) abgncd m irozrn ncm~trc bqurd cry~& kwscnh.mccd ENDOR ugnal mrcnsrtrcs. whrch mdy ad m the mrcrprcta~~on oipowdcr CNDOR spectra obramcd from trJnsnron-mcrJI complckcs III ~ro~rop~cglxses

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The analysis of the Iine'shifts yields ezq;3 Q//I = -2.5 MHz. This result could be rationalized by a population analysis of the nitrogen bonds, The theory predicts that the main contribution to the observed splitting comes from ihc unpzked n-electron.