In the liquid crystal "Phase IV" which exhibits its nematic range between 16 and 76 "C ENDOR spectra of perinaphthenyi and tri-t-butylphencxyl radicals collld be recorded. it is demonstrated that the combined use of the ENDOR and liquid crystal methods yieIds valuabIe structural information.
✦ LIBER ✦
ENDOR study of bis(acetylacetonato)oxovanadium (IV) in frozen liquid crystals
✍ Scribed by Burkhard Kirste; Hans Van Willigen
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 337 KB
- Volume
- 87
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
IN FROZEN LIQUD CRYSTU Burkhard KIRSTE and Hans VAN WILLICEN An ENDOR stud) ofvanadyl biucctylaccIon.nc (VO(xx)2) abgncd m irozrn ncm~trc bqurd cry~& kwscnh.mccd ENDOR ugnal mrcnsrtrcs. whrch mdy ad m the mrcrprcta~~on oipowdcr CNDOR spectra obramcd from trJnsnron-mcrJI complckcs III ~ro~rop~cglxses The ENDOR sp~~ctra estabhsh thal VOW IS present in the form oi an adduct wlh IIIC sohcnt molecules. The adduct formation ma> aKccr rhc ahgnmcnt of Ihe solure molcculcs m tbr hqurd co slal
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