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Endor investigation of the biphenyl and terphenyl anion radicals in solution

✍ Scribed by R. Biehl; K.-P. Dinse; K. Möbius

Publisher
Elsevier Science
Year
1971
Tongue
English
Weight
515 KB
Volume
10
Category
Article
ISSN
0009-2614

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✦ Synopsis

From the ENDOR spectra of the mononegative ions of biphenyl and ortho-, meta-and para-terphenyl in solution complete sets of hyperfiie splitting constants could be determined. The splittings are interpreted in terms of SCJ! MO spin densities obtained from McLachlan tyDe calculations It turns out that n-u soin dekxalization effects do not play a significant role in the spin density distribution in ably from coplanarity.

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