ENDOR and ESR Studies of Radical Cations of Methyl-Substituted Benzene in Halocarbon Matrices
β Scribed by Kadam, R. M.; Itagaki, Y.; Erickson, R.; Lund, A.
- Book ID
- 121406635
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 80 KB
- Volume
- 103
- Category
- Article
- ISSN
- 1089-5639
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π SIMILAR VOLUMES
I4N-and 'H-Coupling constants, determined by ESR, ENDOR, and general-TRIPLE-resonance spectroscopy, are reported for the radical cations of tetrazinodi(heteroarenes) 1-8. The results comply with the expectation that donor properties of these compounds are mainly due to the electron-rich dihydrotetra
The ESR spectra of radical cations of cis-and trans-deealin have been recorded in different halocarbon matrices within the temperature range 4.2 IO 130 K. The ground-state structures of both isomers have been calculated using the UHF/MNDO technique and found to be 'As or ZB, for transdecalin+ and 'A