Applications of ENDOR spectroscopy to radical cations in freon matrixes. 9. The radical cation of benzvalene: an ESR and ENDOR study
โ Scribed by Arnold, Anton; Gerson, Fabian
- Book ID
- 126828730
- Publisher
- American Chemical Society
- Year
- 1991
- Tongue
- English
- Weight
- 284 KB
- Volume
- 113
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
I4N-and 'H-Coupling constants, determined by ESR, ENDOR, and general-TRIPLE-resonance spectroscopy, are reported for the radical cations of tetrazinodi(heteroarenes) 1-8. The results comply with the expectation that donor properties of these compounds are mainly due to the electron-rich dihydrotetra
The cation radical of canthaxanthin was generated electrochemically in dichloromethane and its solution ENDOR spectrum is reported for the first time. The isotropic proton hypertine coupling constants are in reasonable agreement with those calculated by RHF-INDO/SP molecular orbital methods for a pl