## Abstract A series of 6βXβ3,8βdioxatricyclo[3.2.1.0^2,4^]octanes (Xο£ΎCO~2~CH~3~, CN, Cl and CN) are studied by NMR, after their syntheses by epoxidation of the corresponding 7βoxabicyclo[2.2.1]heptenes. The NMR parameters (__J__, Ξ΄) are determined, and also the anisotropy effects of methyl groups
endo-3,8-Dioxatricyclo[3.2.1.02,4]octane-6-carbonitrile
β Scribed by Cossu, M. ;Viani, R. ;Lapasset, J. ;Aycard, J. P. ;Marfisi, C. ;Bodot, H.
- Book ID
- 114503303
- Publisher
- International Union of Crystallography
- Year
- 1986
- Tongue
- English
- Weight
- 194 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0108-2701
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π SIMILAR VOLUMES
The interaction of formally nonconjugated p-orbital systems has been observed in ultraviolet spectra &.g., changes in n + v\* \* and II + II transition energies and intensities for C=C-C-C=0 structures (2) ) as well as in increased rates of carbonium ion reactions (=.g., solvolysia of homoallylic st
The reduction of 3-oxatricyclo[3.2.1.0 2,4 ]octane-endo-6-carbonitrile by lithium aluminum hydride is completed by the formation of exo-2-hydroxy-4-azatricyclo[4.2.1.0 3,7 ]nonane with the structure confirmed (1) by the analysis of 1 H, 13 C, 14 N, and 17 clo[4.2.1.0 3,7 ]nonane prepared by an alter