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Enantiospecific synthesis of optically active natural (+)-conhydrine from (S,S)-tartaric acid

✍ Scribed by Yukio Masaki; Toshihiro Imaeda; Kinnosuke Nagata; Hirohisa Oda; Akichika Ito

Publisher: Elsevier Science
Year: 1989
Tongue: French
Weight: 127 KB
Volume: 30
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)93904-8

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✦ Synopsis

The first enantiospecific synthesis of (+)-conhydrine, one of the poisonous alkaloids of the hemlock was achieved via partial ring opening of 6,8-dJoxabicyclo[3.2.1]octane skeleton prepared from (S,S)-tartaric acid.

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