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Enantioselective Total Synthesis of the Macrocyclic Spermidine Alkaloid (−)-Oncinotine

✍ Scribed by Ina, Hiroji; Ito, Masayuki; Kibayashi, Chihiro


Book ID
127079963
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
299 KB
Volume
61
Category
Article
ISSN
0022-3263

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The Macrocyclic Spermidine Alkaloid (−)-
✍ Sergey A. Sergeyev; Manfred Hesse 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 German ⚖ 109 KB 👁 1 views

## Abstract The total synthesis of the two isomeric macrocyclic enamides **2** and **17** is described. The precursor **14** was synthesized by means of template‐assisted macrocyclization (__Scheme 2__). Isomerization of **14** in the presence of [Fe(CO)~5~] gave **2** and **17** (__Scheme 4__). St