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A Novel Synthesis of the Macrocyclic Spermidine Alkaloid (+)-(S)-Dihydroperiphylline

✍ Scribed by Sergey A. Sergeyev; Manfred Hesse

Publisher
John Wiley and Sons
Year
2002
Tongue
German
Weight
122 KB
Volume
85
Category
Article
ISSN
0018-019X

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## Dedicated to Edgar Heilbronner on the occasion of his 80th birthday The macrocyclic lactam alkaloid (AE)-(2R\*,3R\*)-3-hydroxycelacinnine (1) derived from spermidine was synthesized via stereoselective epoxide-ring opening with magnesium azide and cesium carbonate promoted macrocyclization of t