𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Enantioselective Synthesis of α-Tertiary Hydroxyaldehydes by Palladium-Catalyzed Asymmetric Allylic Alkylation of Enolates

✍ Scribed by Trost, Barry M.; Xu, Jiayi; Reichle, Markus

Book ID
120002722
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
65 KB
Volume
129
Category
Article
ISSN
0002-7863

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Palladium-Catalyzed Asymmetric Allylic A
Palladium-Catalyzed Asymmetric Allylic Alkylation of Ketone Enolates.
✍ Barry M. Trost; Gretchen M. Schroeder 📂 Article 📅 2006 🏛 John Wiley and Sons ⚖ 54 KB 👁 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

Palladium-Catalyzed Asymmetric Allylic A
Palladium-Catalyzed Asymmetric Allylic Alkylation of Ketone Enolates
✍ Barry M. Trost; Gretchen M. Schroeder 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 390 KB 👁 2 views

## Abstract Palladium‐catalyzed asymmetric allylic alkylation of nonstabilized ketone enolates to generate quaternary centers has been achieved in excellent yield and enantioselectivity. Optimized conditions consist of performing the reaction in the presence of two equivalents of LDA as base, one e

Palladium-Catalyzed Diastereoselective a
Palladium-Catalyzed Diastereoselective and Enantioselective Allylic Alkylations of Ketone Enolates
✍ Manfred Braun; Thorsten Meier; Frank Laicher; Panos Meletis; Mesut Fidan 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 297 KB 👁 2 views

## Abstract Lithium and magnesium enolates of cyclohexanone undergo palladium‐catalyzed allylic alkylations under mild conditions. Diastereoselectivity and enantioselectivity are observed when the diphenyl‐ and dimethyl‐substituted allylic substrates **1a** and **1b** are reacted with cyclohexanone