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Enantioselective Synthesis of α-Oxy Amides via Umpolung Amide Synthesis

✍ Scribed by Leighty, Matthew W.; Shen, Bo; Johnston, Jeffrey N.

Book ID
121257480
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
487 KB
Volume
134
Category
Article
ISSN
0002-7863

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## Abstract An efficient and diastereoselective synthesis of α‐amino acids from readily available starting materials has been developed. The key feature of this reaction is an umpolung of a glycine‐derived enolate, providing an alternative approach for the synthesis of α‐amino acids. (© Wiley‐VCH V