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Enantioselective Synthesis of α-Amino Acids from Chiral 1,4-Benzodiazepine-2,5-diones Containing the α-Phenethyl Group

✍ Scribed by Juaristi, Eusebio; León-Romo, José Luis; Ramírez-Quirós, Yara

Book ID
126895313
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
96 KB
Volume
64
Category
Article
ISSN
0022-3263

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Chiral 1, 4-Benzodiazepin-2-one, templat
Chiral 1, 4-Benzodiazepin-2-one, template for enantioselective synthesis of α-amino acids and their α-deuterio congeners. Preliminary communication
✍ Enio Decorte; Roberto Toso; Alessandro Sega; Vitomir Šunjié; Živa Ružić-Toroš; B 📂 Article 📅 1981 🏛 John Wiley and Sons 🌐 German ⚖ 244 KB

## Abstract Absolute conformation of 7‐chloro‐5‐phenyl‐1‐[(__S__)‐α‐phenylethyl]‐1, 3‐dihydro‐2__H__‐1, 4‐benzodiazepin‐2‐one (**1c**) in crystal, and its inversion rate in solution were determined, enabling prognosis of direction of asymmetric induction during C(3)‐alkylation.