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Enantioselective Synthesis of the C(2)-C(11) Cyclopropylfuran Segment of Pinnatin A

✍ Scribed by Tsubuki, Masayoshi; Honda, Toshio; Abekura, Terunobu; Takahashi, Kazunori

Book ID
119940493
Publisher
Japan Institute of Heterocyclic Chemistry
Year
2010
Tongue
English
Weight
1019 KB
Volume
82
Category
Article
ISSN
0385-5414

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Enantioselective synthesis of the C11–C1
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✍ Yeyu Cao; Ahmad Farouk Eweas; William A Donaldson πŸ“‚ Article πŸ“… 2002 πŸ› Elsevier Science 🌐 French βš– 322 KB

The C11-C17 segment of the antifungal agent soraphen A 1a was prepared from glyceraldehyde acetonide in nine steps. The C12 stereocenter is derived from glyceraldehyde, while the C17 stereocenter as introduced by 1,6-asymmetric control via the coordinated Fe(CO) 3 .