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Enantioselective synthesis of polyketide segments through vinylogous Mukaiyama aldol reactions

✍ Scribed by Serkan Simsek; Markus Kalesse

Book ID
104096396
Publisher
Elsevier Science
Year
2009
Tongue
French
Weight
292 KB
Volume
50
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES

Organocatalyzed Highly Enantioselective
Organocatalyzed Highly Enantioselective and anti-Selective Construction of Ξ³-Butenolides through Vinylogous Mukaiyama Aldol Reaction
✍ Ning Zhu; Bao-Chun Ma; Yong Zhang; Wei Wang πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons 🌐 English βš– 177 KB πŸ‘ 1 views

## Abstract The formation of chiral γ‐butenolides has been achieved with good yields (up to 90%), high enantioselectivity (up to 91%) and diastereoselectivity (up to 9/1, __anti__‐selective) through an organocatalyzed vinylogous Mukaiyama aldol reaction of 2‐(trimethylsilyloxy)furan and aldehydes.