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ChemInform Abstract: Organocatalyzed Highly Enantioselective and anti-Selective Construction of γ-Butenolides Through Vinylogous Mukaiyama Aldol Reaction.

✍ Scribed by Ning Zhu; Bao-Chun Ma; Yong Zhang; Wei Wang

Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
41
Category
Article
ISSN
0931-7597

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Organocatalyzed Highly Enantioselective
Organocatalyzed Highly Enantioselective and anti-Selective Construction of γ-Butenolides through Vinylogous Mukaiyama Aldol Reaction
✍ Ning Zhu; Bao-Chun Ma; Yong Zhang; Wei Wang 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 177 KB

## Abstract The formation of chiral γ‐butenolides has been achieved with good yields (up to 90%), high enantioselectivity (up to 91%) and diastereoselectivity (up to 9/1, __anti__‐selective) through an organocatalyzed vinylogous Mukaiyama aldol reaction of 2‐(trimethylsilyloxy)furan and aldehydes.