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Enantioselective Synthesis of Poison-Frog Alkaloid 237D (I) and Determination of Absolute Stereochemistry.

โœ Scribed by Naoki Toyooka; Masashi Kawasaki; Hideo Nemoto; John W. Daly; Thomas F. Spande; H. Martin Garraffo


Publisher
John Wiley and Sons
Year
2005
Weight
9 KB
Volume
36
Category
Article
ISSN
0931-7597

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โœ I. SHIINA; Y. FUKUDA; T. ISHII; H. FUJISAWA; T. MUKAIYAMA ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 31 KB ๐Ÿ‘ 2 views

Determination of Relative and Absolute Stereochemistry of Cephalosporolide D and Its Enantioselective Total Synthesis. -The title compound (XI) is synthesized in an efficient approach via an aldol reaction of (II) and (III) as key step. (R)-(I) is obtained from commercially available methyl (R)-3-h