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Enantioselective Synthesis of Ferrocenyl Nucleoside Analogues with Apoptosis-Inducing Activity

✍ Scribed by James, Philippe; Neudörfl, Jörg; Eissmann, Moritz; Jesse, Patrick; Prokop, Aram; Schmalz, Hans-Günther

Book ID
120513856
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
200 KB
Volume
8
Category
Article
ISSN
1523-7060

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We have previously demonstrated that h 4 -butadiene-Fe(CO) 3 complexes of type 1 undergo highly selective substitution reactions at the acetal center via Fe(CO) 3 -stabilized cationic intermediates of type 2. [1] As an example, the SnCl 4 -catalyzed reaction of complex 1 (R = H) with a silylated ura