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Enantioselective Synthesis of anti-β-Hydroxy-α-Amido Esters by Asymmetric Transfer Hydrogenation in Emulsions

✍ Scribed by Brinton Seashore-Ludlow; Piret Villo; Prof. Peter Somfai

Book ID
112020020
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
349 KB
Volume
18
Category
Article
ISSN
0947-6539

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Highly enantioselective synthesis of ant
Highly enantioselective synthesis of anti aryl β-hydroxy α-amino esters via DKR transfer hydrogenation
✍ Zhuqing Liu; C.Scott Shultz; Candice A. Sherwood; Shane Krska; Peter G. Dormer; 📂 Article 📅 2011 🏛 Elsevier Science 🌐 French ⚖ 456 KB

An efficient preparation of highly enantiomerically enriched aryl b-hydroxy a-amino esters via dynamic kinetic resolution (DKR), asymmetric transfer hydrogenation of a-amino b-keto esters is described. The anti b-hydroxyl a-amino esters were obtained both in high yields and high diasteroselectivity.