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Enantioselective Synthesis of 4-Substituted 2-Pyrrolidinones by Site-selective C-H Insertion of α-Methoxycarbonyl-α-diazoacetanilides Catalyzed by Dirhodium(II) Tetrakis[N-phthaloyl-(S)-tert-leucinate]

✍ Scribed by Masahiro Anada; Shun-ichi Hashimoto


Book ID
104258459
Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
709 KB
Volume
39
Category
Article
ISSN
0040-4039

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ChemInform Abstract: Highly Enantioselec
✍ M. ANADA; N. WATANABE; S. HASHIMOTO 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 42 KB 👁 2 views

Highly Enantioselective Construction of the Key Azetidin-2-ones for the Synthesis of Carbapenem Antibiotics via Intramolecular C-H Insertion Reactions of α-Methoxycarbonyl-α-diazoacetamides Catalyzed by Chiral Dirhodium(II) Carboxylates. -The title reaction of compounds (I) and (III) to afford bicy