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ChemInform Abstract: Enantioselective Synthesis of 4-Substituted 2-Pyrrolidinones by Site-Selective C—H Insertion of α-Methoxycarbonyl-α-diazoacetanilides Catalyzed by Dirhodium(II) Tetrakis[N-phthaloyl-(S)-tert-leucinate].

✍ Scribed by M. ANADA; S. HASHIMOTO


Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
29
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Highly Enantioselec
✍ M. ANADA; N. WATANABE; S. HASHIMOTO 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 42 KB 👁 2 views

Highly Enantioselective Construction of the Key Azetidin-2-ones for the Synthesis of Carbapenem Antibiotics via Intramolecular C-H Insertion Reactions of α-Methoxycarbonyl-α-diazoacetamides Catalyzed by Chiral Dirhodium(II) Carboxylates. -The title reaction of compounds (I) and (III) to afford bicy