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Enantioselective synthesis of 1(R)-trans-chrysanthemic acid

✍ Scribed by Alain Krief; Laurent Provins; Alexandre Froidbise

Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
116 KB
Volume
43
Category
Article
ISSN
0040-4039

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Asymmetric synthesis of [C-1-3H]-labelle
Asymmetric synthesis of [C-1-3H]-labelled (+)-trans [1R,3R]-chrysanthemic acid
✍ Gerald Pattenden; Richard Storer πŸ“‚ Article πŸ“… 1976 πŸ› John Wiley and Sons 🌐 French βš– 212 KB

## Abstract A facile asymmetric synthesis of [C‐1‐^3^H]‐labelled (+)‐trans[1R,3R]‐chrysanthemic acid, required for biosynthetic studies is described. The tritium labelled acid is prepared from the corresponding (βˆ’)‐cis[1S,3R]‐ester by selective epimerisation of the C‐1 centre in the latter, in the