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Enantioselective Ring-Opening Reaction of m eso- Epoxides with ArSeH Catalyzed by Heterometallic Ti−Ga−Salen System

✍ Scribed by Yang, Minghua; Zhu, Chengjian; Yuan, Fang; Huang, Yijun; Pan, Yi

Book ID
117990002
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
74 KB
Volume
7
Category
Article
ISSN
1523-7060

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Enantioselective ring-opening reaction o
Enantioselective ring-opening reaction of meso-epoxides with ArSH catalyzed by heterobimetallic Ti–Ga–Salen system
✍ Jiangtao Sun; Fang Yuan; Minghua Yang; Yi Pan; Chengjian Zhu 📂 Article 📅 2009 🏛 Elsevier Science 🌐 French ⚖ 166 KB

a Unless otherwise noted, the reaction condition: cyclohexene oxide (1 mmol), PhSH (1.2 mmol), catalyst (10 mol %). b Isolated yields. c Determined by HPLC with a Daicel Chiralcel OD column. Absolute configurations of the major enantiomers (1S,2S) were assigned by comparison of the rotation values