Enantioselective rhodium catalyzed hydroboration of olefins using chiral bis(aminophosphine) ligands

✍ Scribed by Jean-Michel Brunel; Gérard Buono

• Book ID: 104261322
• Publisher: Elsevier Science
• Year: 1999
• Tongue: French
• Weight: 180 KB
• Volume: 40
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(99)00538-9

✦ Synopsis

The synthesis of new chiral bis(aminopho6"phine) ligands 1-5 was achieved and assessed in the enantiosclective rhodium catalyzed hydroboration of various olefins with catecholborane.

Enantiosclectivities up to 77% were obtained.