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Enantioselective Reductions of β-keto-Esters by Bakers' Yeast

✍ Scribed by CHARLES J. SIH; BING-NAN ZHOU; ARAVAMUDAN S. GOPALAN; WOAN-RU SHIEH; CHING-SHIH CHEN; GARY GIRDAUKAS; FRANK VANMIDDLESWORTH


Book ID
118721900
Publisher
John Wiley and Sons
Year
1984
Tongue
English
Weight
375 KB
Volume
434
Category
Article
ISSN
0890-6564

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Enantioselective reduction of β-keto est
✍ Douglass F Taber; Lee J Silverberg 📂 Article 📅 1991 🏛 Elsevier Science 🌐 French ⚖ 266 KB

Highly enantioselective reduction of P\_keto esters with BINAPeRu catalyst can be effected at 50 psig H2 and 800, using a Parr shaker. A simplified preparation of the BINAP.Ru catalyst is reported. In 1987 the Nagoya and Takasago groups, working in collaboration, reported 1\*2 that a catalyst prepa