Enantioselective Reduction of Prochiral Ketones Using Spiroborate Esters as Catalysts.
โ Scribed by Viatcheslav Stepanenko; Melvin De Jesus; Wildeliz Correa; Irisbel Guzman; Cindybeth Vazquez; Wilanet de la Cruz; Margarita Ortiz-Marciales; Charles L. Barnes
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 38 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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โฆ Synopsis
Abstract
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๐ SIMILAR VOLUMES
## Abstract Asymmetric catalytic activity of the chiral spiroborate esters **1**โ**9** with a O~3~BN framework (see __Fig.โ 1__) toward borane reduction of prochiral ketones was examined. In the presence of 0.1โ equiv. of a chiral spiroborate ester, prochiral ketones were reduced by 0.6โ equiv. of bor