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Enantioselective photodeconjugation of α,β-unsaturated esters: Effect of the nature of the chiral agent

✍ Scribed by O. Piva; F. Henin; J. Muzart; J.-P. Pete

Book ID
104218783
Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
199 KB
Volume
27
Category
Article
ISSN
0040-4039

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A very enantioselective photodeconjugati
A very enantioselective photodeconjugation of α,β-unsaturated esters
✍ Olivier Piva; Françoise Henin; Jacques Muzart; Jean-Pierre Pete 📂 Article 📅 1987 🏛 Elsevier Science 🌐 French ⚖ 213 KB

An enantiomeric excess up to 70% can be obtained in the photodeconjugation of conjugated esters in the presence of (1 R, 2s) I-phenyl, 2-isopropylamino-propanol. It was shown previously that chiral b,y-unsaturated esters can be produced when conjugated