A very enantioselective photodeconjugation of α,β-unsaturated esters

✍ Scribed by Olivier Piva; Françoise Henin; Jacques Muzart; Jean-Pierre Pete

• Book ID: 104227934
• Publisher: Elsevier Science
• Year: 1987
• Tongue: French
• Weight: 213 KB
• Volume: 28
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)96635-8

✦ Synopsis

An enantiomeric excess up to 70% can be obtained in the photodeconjugation of conjugated esters in the presence of (1 R, 2s) I-phenyl, 2-isopropylamino-propanol.

It was shown previously that chiral b,y-unsaturated esters can be produced when conjugated