𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Enantioselective ortho lithiation of tricarbonyl(masked phenol and aniline)chromium complexes

✍ Scribed by Motokazu Uemura; Yoshinori Hayashi; Yuji Hayashi

Book ID
108036216
Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
305 KB
Volume
5
Category
Article
ISSN
0957-4166

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Enantioselective Deprotonation/Electroph
Enantioselective Deprotonation/Electrophile Addition Reactions of Tricarbonyl(phenyl carbamate)chromium Complexes
✍ Anna Quattropani; GΓ©rald Bernardinelli; E. Peter KΓΌndig πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 German βš– 239 KB πŸ‘ 1 views

Sequential reaction of the tricarbonyl[(h 6 -phenyl) carbamate]chromium complex 3 with chiral amide bases (see 4 and 5) and electrophiles yielded planar chiral ortho-substituted complexes 6 with up to 70% enantiomeric excess (ee) (Scheme 2, Table 1 and2). The enantiomer purity could be increased to

ChemInform Abstract: Enantioselective De
ChemInform Abstract: Enantioselective Deprotonation/Electrophile Addition Reactions of Tricarbonyl(phenyl carbamate)chromium Complexes.
✍ Anna Quattropani; Gerald Bernardinelli; E. Peter Kuendig πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 35 KB πŸ‘ 1 views

Enantioselective Deprotonation/Electrophile Addition Reactions of Tricarbonyl(phenyl carbamate)chromium Complexes. -Optimized conditions are elaborated for the preparation of chiral ortho-substituted complexes staring from racemic complex (I). The enantiomeric purity of the products can be increase