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Synthesis and Characterization of Diethynylated Tricarbonyl(cyclobutadiene)iron Complexes: The ortho-Lithiation Concept

✍ Scribed by Wiegelmann, Jutta E. C.; Bunz, Uwe H. F.; Schiel, Patricia


Book ID
127110029
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
348 KB
Volume
13
Category
Article
ISSN
0276-7333

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The I-dimethoxymethyl-5,6-dimethylidene-7-oxabicyclo[2.2. I jhept-2-ene (9) has been prepared. On treatment with Fe,(CO),, the endocyclic double bond C(2)=C(3) was coordinated first giving the Corresponding exo-Fe(C0)4 complex 10. The latter reacted with Fe,(CO), and afforded cis-heptacarbonyl-p -[(