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Enantioselective Organocatalytic Allylic Amination

✍ Scribed by Poulsen, Thomas B.; Alemparte, Carlos; Jørgensen, Karl Anker

Book ID
125892741
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
82 KB
Volume
127
Category
Article
ISSN
0002-7863

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Organocatalytic α-amination–allylation-R
Organocatalytic α-amination–allylation-RCM strategy: enantioselective synthesis of cyclic hydrazines
✍ Aram Lim; Jung Hoon Choi; Jinsung Tae 📂 Article 📅 2008 🏛 Elsevier Science 🌐 French ⚖ 193 KB

A highly enantioselective method for the synthesis of cyclic hydrazines by using organocatalytic a-amination-allylation-RCM strategy is described. Proline-catalyzed a-amination of aldehydes followed by indium-mediated one-pot allylation of the crude a-hydrazino aldehydes produces 1,2-aminoalcohols i