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Enantioselective Iridium-Catalyzed Vinylogous Reformatsky-Aldol Reaction from the Alcohol Oxidation Level: Linear Regioselectivity by Way of Carbon-Bound Enolates

✍ Scribed by Abbas Hassan; Jason R. Zbieg; Prof. Michael J. Krische

Publisher: John Wiley and Sons
Year: 2011
Tongue: English
Weight: 300 KB
Volume: 50
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.201100646

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Enantioselective Iridium-Catalyzed Vinyl

Enantioselective Iridium-Catalyzed Vinylogous Reformatsky-Aldol Reaction from the Alcohol Oxidation Level: Linear Regioselectivity by Way of Carbon-Bound Enolates

✍ Abbas Hassan; Jason R. Zbieg; Prof. Michael J. Krische 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 310 KB 👁 1 views

Scheme 1. Catalytic enantioselective vinylogous aldol reactions. PG = protecting group. Scheme 2. Carbonyl addition by way of primary s-ally haptomers typically generates branched products as anti-diastereomers.

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