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Enantioselective Hydrogenation of Ketopantolactone

✍ Scribed by M. Schürch; O. Schwalm; T. Mallat; J. Weber; A. Baiker

Book ID
112254989
Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
565 KB
Volume
169
Category
Article
ISSN
0021-9517

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Synthetic Modifiers for Platinum in the
Synthetic Modifiers for Platinum in the Enantioselective Hydrogenation of Ketopantolactone: A Test for the Mechanistic Models of Ketone Hydrogenation
✍ Elisabeth Orglmeister; Tamas Mallat; Alfons Baiker 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 142 KB 👁 1 views

Various derivatives of (R)-1-(1-naphthyl)ethylamine have been synthesized and tested as chiral modifiers of Pt/alumina in the enantioselective hydrogenation of ketopantolactone. The best modifiers (ee up to 79%) possess an ester function in the a-position to the amino group. The modifiers performed