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Enantioselective Hydrogenation of Ketopantolactone: Effect of Stereospecific Product Crystallization during Reaction

✍ Scribed by M. Schürch; N. Künzle; T. Mallat; A. Baiker

Book ID
112255335
Publisher
Elsevier Science
Year
1998
Tongue
English
Weight
65 KB
Volume
176
Category
Article
ISSN
0021-9517

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## Abstract Enantioselective syntheses of several paraconic acids have been achieved using catalyzed asymmetric hydrogenation of β‐keto esters with SYNPHOS^®^ as a ligand. This strategy allowed the short synthesis of biologically active (−)‐methylenolactocin **1**, (−)‐protolichesterinic acid **2**