Enantioselective hydrogenation of enamides catalyzed by chiral rhodium–monodentate phosphite complexes
✍ Scribed by Manfred T. Reetz; Gerlinde Mehler; Andreas Meiswinkel; Thorsten Sell
- Publisher
- Elsevier Science
- Year
- 2002
- Tongue
- French
- Weight
- 173 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0040-4039
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📜 SIMILAR VOLUMES
## Abstract For Abstract see ChemInform Abstract in Full Text.
The monodentate phosphoramidite ligand monophos was used in the Rh-catalyzed asymmetric hydrogenation of enamides to give high enantioselectivities (up to 96% ee).
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
## Abstract The rhodium‐catalyzed asymmetric hydrogenation of different acyclic and cyclic __N__‐acyl enamides to give __N__‐acyl‐protected optically active amines has been examined for the first time in detail in the presence of chiral monodentate 4,5‐dihydro‐3__H__‐dinaphthophosphepines **5a**–**