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Enantioselective epoxidation of α,β-unsaturated ketones using polymer-supported lanthanoid–BINOL complexes

✍ Scribed by Doss Jayaprakash; Yukari Kobayashi; Shizue Watanabe; Takayoshi Arai; Hiroaki Sasai


Publisher
Elsevier Science
Year
2003
Tongue
English
Weight
132 KB
Volume
14
Category
Article
ISSN
0957-4166

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Chiral bioinspired iron complexes of N 4 ligands based on the ethylenediamine backbone display remarkable levels of enantioselectivity for the first time in the asymmetric epoxidation of a,b-unsaturated ketones using hydrogen peroxide (up to 87% ee) or peracetic acid as oxidant, respectively. Notabl