ChemInform Abstract: Stabilized α-Helix-Catalyzed Enantioselective Epoxidation of α,β-Unsaturated Ketones.
✍ Scribed by Masanobu Nagano; Mitsunobu Doi; Masaaki Kurihara; Hiroshi Suemune; Masakazu Tanaka
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 36 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0931-7597
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## Abstract Under optimized conditions, a variety of ketones undergo asymmetric 1,2‐reductions almost exclusively instead of the normally observed 1,4‐reductions in the presence of in situ‐generated CuH which is ligated with an optically active bisphosphane ligand.
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