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Enantioselective Diels–Alder Approach to Angucyclinones from (S)-2-(p-Tolylsulfinyl)-1,4-naphthoquinone and Substituted Racemic Vinylcyclohexenes

✍ Scribed by Dr. M. Carmen Carreño; Dr. Antonio Urbano; Prof. Jean Fischer

Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
422 KB
Volume
36
Category
Article
ISSN
0044-8249

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Chiral racemic vinylcyclohexenes 2, bearing oxygenated substituents and/or a methyl group at the C-5 position of the cyclohexene ring, were submitted to Diels-Alder reactions with enantiomerically pure (SS)-(2-p-tolylsulfinyl)-1,4-naphthoquinone [(+)-1]. The domino cycloaddition/pyrolytic sulfoxide